When 100mLHCl is added to 35mLNaOH, 35mLHCl is utilised to neutralise NaOH, while 65mLHCl remains as such. Hence, the solution becomes acidic. In acid solution, the colour of methyl orange (indicator) is red due to presence of Me+ions as methyl orange (yellow)MeOH⇌redMe++OH−