Q.
0.6mL of acetic acid (CH3COOH), having density 1.06gmL−1, is dissolved in 1 litre of water. The depression in freezing point observed for this strength of acid was 0.0205∘C. The van’t Hoff factor is
Mass of acetic acid w2= Volume × Density =0.6×1.06=0.636g
We know, ΔT=i×Kf×M2×w1w2×1000 ...(i)
Given, ΔT=0.0205,Kf=1.86Kkg mol −1,w2=0.636g M2=60g mol −1,w1=1000g (Mass of 1 litre water) Putting these values in eqn. (i), we get 0.0205=i×1.86×60×10000.636×1000 i=1.03397