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Q. Write the balanced equations involved in the preparation of
(i) bleaching powder from slaked lime
(ii) nitric oxide from nitric acid
(iii) chlorine from sodium chloride
(iv) anhydrous aluminium chloride from alumina

IIT JEEIIT JEE 1979The p-Block Elements - Part2

Solution:

(i) $Ca(OH)_2 + Cl_2 \xrightarrow{40^\circ\, C} CaOCl_2 + H_2O$
(ii) $3Cu + 8HNO_3 (dil) \longrightarrow 3Cu(NO_3 )_2+ 4H_2O + 2NO$
(iii) $2NaCl + 2H_2SO_4 + MnO_2 \longrightarrow Na_2SO_4 + MnSO_4 + 2H_2O + Cl_2$
(iv) $Al_2O_3 + 3C + 3Cl_2 \xrightarrow{\, \, \Delta\, \, } 2AlCl_3 + 3CO$