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Q. Work done to increase the temperature of one mole of an ideal gas by $30^{\circ} C$, if it is expanding under the condition $V \propto T^{2 / 3}$ is, $(R=8.314 \,J / mol / K )$

EAMCETEAMCET 2012

Solution:

We have, $V \propto T^{2 / 3}$
and $p \propto \sqrt{V}$
$\therefore p=k \sqrt{V} $
$\Rightarrow p=k V^{1 / 2}$
Work done, $W=\int p d V$
$W=\int k V^{1 / 2}$
$W=\frac{k V^{3 / 2}}{3 / 2}$
$W=\frac{2}{3} \frac{p}{\sqrt{V}} V^{3 / 2}=\frac{2}{3} p V \left[\because V=\frac{p}{\sqrt{V}}\right]$
$=\frac{2}{3} n R T=\frac{2}{3} \times 1 \times 8.3 \times 30=166.2 \,J$