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Q. Which will form maximum boiling point azeotrope

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Solution:

The solutions (liquid mixture) which boils at constant temperature and can distil as such without any change in composition are called azeotropes.
Solution of $HNO _3$ and $H _2 O$ will form maximum boiling point azeotrope. Maximum boiling azeotropes show negative deviation from Raoult's law.
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Boiling point of the azeotrope of these two solutions is $393.5 \,K$