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Chemistry
Which pair is not correct order of lattice energy?
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Q. Which pair is not correct order of lattice energy?
Chemical Bonding and Molecular Structure
A
$KCl > MgO$
73%
B
$AlN > MgO$
14%
C
$CaO > BaO$
7%
D
$MgCO _{3}> CaCO _{3}$
7%
Solution:
Larger the charge on cation and anion, larger the polarising power and thus larger the covalent nature and such compounds have larger lattice energy.
$\begin{matrix}K^{+}>Mg^{2+}&Size&Cl^{-}>O^{2-}&Size\\ +1 \,\,\,+2&charge&-1 <2-&charge\end{matrix}$
Thus, $MgO$ is less ionic than $KCl$ thus lattice energy of $MgO$ is larger than that of $KCl$.
Thus, given order is incorrect.