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Q. Which order for basic character of amine is correct for following compounds?

Question

NTA AbhyasNTA Abhyas 2020Organic Chemistry – Some Basic Principles and Techniques

Solution:

Electron releasing group increases basic character of amine and aromatic amine is less basic than aliphatic amine

Basic order $ \propto \, +I$ or $+M$ effect $ \propto \frac{1}{- I}$ or $-\frac{1}{M}$ effect

Aliphatic amine is more basic than aromatic amine

Solution