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Q. Which one of the following will be most basic?

KEAMKEAM 2000

Solution:

Benzyl amine will be the most basic among these because in benzylamine the lone pair of electron on the N-atom is not conjugated with the benzene ring and hence, it is not delocalized.Therefore, the lone pair of electrons on the N-atom is easily available for protonadon than that of arylamines.