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Q. Which one of the following is not a primary amine?

KEAMKEAM 2012Amines

Solution:

Dimethylamine $\left[\left( CH _{3}\right)_{2} NH \right]$ is a secondary amine as the central Nitrogen atom is substituted by two methyl groups and the nitrogen has one hydrogen. Tert-butyl amine, secondary butyl amine, isobutylamine are all the isomers of $n$-butyl amine, varying in the position of the $N$ - group in the alkyl chain.
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