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Chemistry
Which one of the following halogen compounds is difficult to be hydrolysed by SNI mechanism?
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Q. Which one of the following halogen compounds is difficult to be hydrolysed by S
N
I mechanism?
KEAM
KEAM 2013
A
Tertiary butyl chloride
B
Isopropyl chloride
C
Benzyl chloride
D
Chlorobenzene
E
Allyl chloride
Solution:
$C - Cl$ bond in chloro benzene is stable due to delocalisation of electrons by resonance. Also, $(C-Cl) $ bond posses a double bond character due to which it is very difficult to hydrolysed it by $S _{ N } 1$ mechanism.