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Chemistry
Which one of the following forms an aldehyde and then an acid on heating with acidified potassium permanganate?
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Q. Which one of the following forms an aldehyde and then an acid on heating with acidified potassium permanganate?
COMEDK
COMEDK 2011
Alcohols Phenols and Ethers
A
sec-Butyl alcohol
11%
B
tert-Butyl alcohol
33%
C
Butyl alcohol
37%
D
Isopropyl alcohol
19%
Solution:
Since, butyl alcohol is a primary alcohol, it first gives an aldehyde and then carboxylic acid on oxidation. While, secondary and tertiary alcohols first give ketones and then carboxylic acids on oxidation.