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  4. Which one of the following chlorohydrocarbons readily undergoes solvolysis?

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Q. Which one of the following chlorohydrocarbons readily undergoes solvolysis?

J & K CETJ & K CET 2008Haloalkanes and Haloarenes

Solution:

Solvolysis is related to stability of carbocation formed and among these benzyl carbocation is most stable. So, it will undergo solvolysis readily.