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  4. Which one of the following alkyl halides has the lowest boiling point?

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Q. Which one of the following alkyl halides has the lowest boiling point?

KEAMKEAM 2012Haloalkanes and Haloarenes

Solution:

The boiling points of alkyl chlorides increases with the increase of the size of alkyl group. In a group of isomeric alkyl chloride, the order of boiling point is Primarygtsecondarygttertiary.