Addition' is a binary operation on $N$.
Under $+, N$ has no identity element
Under this operation, $G$ is an abelian group. 'subtraction' is a binary operation on the set $Z$. But $a-(b-c) \neq(a-b)-c$.
The operation $*$ defined on $N$ by $a * b = a ^{ b }+ b ^{ a }$ is both binary and commutative. But this is not associative (verify this ).