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  4. Which on reduction does not give primary amines?

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Q. Which on reduction does not give primary amines?

Rajasthan PMTRajasthan PMT 2004

Solution:

Isocyanides (carbylamines) on reduction give $2^{\circ}$ amines.
$R - NC \stackrel{ H _{2} / Ni }{\longrightarrow } \underset{2^{\circ}\text{amine}}{R - NHCH _{3}}$