Q.
Which of them is correct order for solvolysis rate in aqueous acetone? (via $S _{N}1$)
$CH_3O - CH = CH - CH_2-Cl$
P
$CH_3 - O - \underset{\overset{||}{C}H_2}{C}-CH_2 - Cl$
Q
$CH_3O-CH_2-CH=CH-Cl$
R
$CH_3O-CH_2-CH_2=CH-Cl$
S
| $CH_3O - CH = CH - CH_2-Cl$ | P |
| $CH_3 - O - \underset{\overset{||}{C}H_2}{C}-CH_2 - Cl$ | Q |
| $CH_3O-CH_2-CH=CH-Cl$ | R |
| $CH_3O-CH_2-CH_2=CH-Cl$ | S |
Haloalkanes and Haloarenes
Solution: