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Q.
Which of the following transition metal ions is not coloured?
AFMCAFMC 2010The d-and f-Block Elements
Solution:
Presence of unpaired electron is a necessity for transition metal ions to give colour.
The electronic configuration of given transition metal ions are as
${ }_{29} Cu ^{+} =[ Ar ] 3 d^{10} 4 s^{0}$ (no unpaired electron)
${ }_{23} V ^{3+} =[ Ar ] 3 d^{2} 4 s^{0} $ (two unpaired electrons)
${ }_{27} Co ^{2+} =[ Ar ] 3 d^{7} 4 s^{0} $ (three unpaired electrons)
${ }_{28} Ni ^{2+} =[ Ar ] 3 d^{8} 4 s^{0} $ (two unpaired electrons)
Thus, $Cu ^{+}$ion is colourless.