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Q. Which of the following statements are correct?
(i) The second period $(n=2)$ starts with lithium and third electron enters the $2 s$ orbital.
(ii) Successive filling of $3 s$ and $3 p$ orbitals gives rise to the third period of 8 elements from sodium to argon.
(iii) The fourth period $(n=4)$ starts at potassium and the added electron fill up first $4 s$ and $4 p$ orbitals then $3 d$ orbital is filled.
(iv) Fifth period begins with rubidium with the filling of $5 s$ orbital and ends at xenon with the filling up of the $5 p$ orbital.

Classification of Elements and Periodicity in Properties

Solution:

In fourth period filling up of $3d$ orbital becomes energetically favourable before the $4p$ orbital is filled.