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Q. Which of the following species is not paramagnetic ?

JEE MainJEE Main 2017Chemical Bonding and Molecular Structure

Solution:

CO has 14 electrons (even) $\therefore $ it is diamagnetic

NO has $15 e ^{-}$ (odd) $\therefore $ it is paramagnetic and has 1 unpaired electron in $\pi^{*} 2 p$ molecular orbital.

$B _{2}$ has $10 e ^{-}$ (even) but still paramagnetic and has two unpaired electrons in $\pi 2 p_{x}$ and $\pi 2 p_{y}$ (s-p mixing).

$O _{2}$ has $16 e ^{-}$ (even) but still paramagnetic and has two unpaired electrons in $\pi^{\star} 2 p_{x}$ and $\pi^{\star} 2 p_{y}$ molecular orbitals.