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Q. Which of the following sets of quantum numbers is correct ?

UPSEEUPSEE 2009

Solution:

For a given electron,
Principal quantum number, $n=0,1,2,3, \ldots$

azimuthal quantum number, $l=0$ to $(n-1)$,

magnetic quantum number, $m=-l$ to $+l$ and spin quantum number, $s=\pm \frac{1}{2}$

When, $n=5, l=0,1,2,3$ or $4$ and $m=-4$ to $+4$

$\therefore n=5, l=4, m=0, s=+\frac{1}{2}$ is a correct set of quantum numbers.