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Q. Which of the following set of quantum number is correct for an electron in 5f orbital?

NTA AbhyasNTA Abhyas 2020Structure of Atom

Solution:

Any sub-orbit is represented as nl such that n is the principle quantum number (in the form of values) and l is the azimuthal quantum number (its name).
Value of $l < n$ $l$ $0$ $1$ $2$ $3$ $4$
s p d f g


Value of m: -l to +l including 0,

Value of s: $+\frac{1}{2}$ or $-\frac{1}{2}$

for 5f: n = 5, l = 3, m = any value between -3 to +3.

Hence n = 5, l = 3, m = +1, s = $+\frac{1}{2}$ is the correct set. In other options these conditions are not satisfied so they are incorrect.