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Q. Which of the following reagent evolves nitrogen on reaction with ethyl amine?

Rajasthan PETRajasthan PET 2003

Solution:

$ \underset{ethylamine}{\mathop{{{C}_{2}}{{H}_{5}}N{{H}_{2}}}}\,+\underset{\begin{smallmatrix} nitrosyl \\ chloride \end{smallmatrix}}{\mathop{NOCl}}\,\xrightarrow[{}]{{}}\underset{\begin{smallmatrix} chloro \\ ethane \end{smallmatrix}}{\mathop{{{C}_{2}}{{H}_{5}}Cl}}\,+{{N}_{2}}+{{H}_{2}}O $