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Q. Which of the following reactions are disproportionation reactions?
(I) $Cu^+ \to Cu^{2+} + Cu$
(II) $3MnO_4^- + 4H^+ \to 2MnO_4^- + MnO_2 + 2H_2O$
(III) $2KMnO_4 \to K_2MnO_4 + MnO_2 + O_2$
(IV) $2MnO_4^- + 3Mn^{2+} + 2H_2O \to 5MnO_2 + 4H^+$

The d-and f-Block Elements

Solution:

In $(I)$, $Cu^+$ is oxidised as well as reduced. In $(II)$, $MnO_4^-$ ions are oxidised as well as reduced.