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Q.
Which of the following reaction is possible at anode?
Electrochemistry
Solution:
The anode is the electrode where oxidation (loss of electrons) takes place; in a galvanic cell, it is the negative electrode, as when oxidation occurs, electrons are left behind on the electrode.
The cathode is the electrode where reduction (gain of electrons) takes place; in a galvanic cell, it is the positive electrode, as less oxidation occurs, fewer ions go into solution, and fewer electrons are left on the electrode.
So, in the reaction $2 Cr ^{3+}+7 H _{2} O \rightarrow Cr _{2} O _{7}^{2-}+14 H ^{+}$
Cr is getting oxidised as the oxidation state is changing from $+3$ to $+6$ and hence this reaction is possible at anode.