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Q. Which of the following oxides can act both as an oxidising agent as well as reducing agent ?

MHT CETMHT CET 2019

Solution:

$SO _{2}$ oxides can act both as an oxidising agent as well as reducing agent. It behaves as a reducing agent in moist conditions. It convert iron (III) ions to iron (II) ions and decolourises acidified potassium permanganate (VII) solution.

$2 F e ^{3+}+ SO _{2}+2 H _{2} O \longrightarrow 2 Fe ^{2+}+ SO _{4}^{2-}+4 H ^{+}$

When $SO _{2}$ reacts with $H _{2} S$, it produces sulphur and water. In this reaction, '$SO_2$, act as an oxidising agent.

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