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  4. Which of the following isomers will give white precipitate with BaCl2 solution?

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Q. Which of the following isomers will give white precipitate with $BaCl_{2}$ solution?

Coordination Compounds

Solution:

$[Co(NH_{3})_{5}Br]SO_{4} {\rightleftharpoons} [Co(NH_{3})_{5}Br]^{2+}+SO^{2-}_{4}$
$SO^{2-}_{4}+BaCl_{2} \to \underset{\text{white ppt.}}{BaSO_{4}}+2Cl^{-}$