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Chemistry
Which of the following is the most basic ?
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Q. Which of the following is the most basic ?
UPSEE
UPSEE 2012
Amines
A
21%
B
9%
C
7%
D
63%
Solution:
Lone pair of electrons present at $N$ in $( a )$ is in $s p^{2}$ -hybrid orbital (less available).
Lone pair of electrons present at $N$ in $( b )$ is in hyperconjugation with benzene ring therefore, these are also less available.
Aniline is less basic in nature.
Lone pair of electrons of $N$ in (d) are available freely. So, this compound is the most basic.