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Q. Which of the following is the correct and increasing order of lone pair of electrons on the central atom?

BITSATBITSAT 2018

Solution:

The number of lone pairs of electrons on central atom in various given species are
Species Number of lone pairs on central atom
$IF_7$ nil
$IF_5$ 1
$ClF_3$ 2
$XeF_2$ 3

Thus the correct increasing order is
$\underset{ 0}{IF_7 } < \underset{ 1}{IF_5 }< \underset{ 2}{ClF_3 } < \underset{3}{ X eF_2}$