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Q.
Which of the following is correct method to convert $p$-toluidine to $p$-toluic acid?
Amines
Solution:
Toluene on nitrification gives $p$-nitro toluene, which on reduction with $Sn / HCl$ gives $p -$ toluidine diazonium chloride salt, this on reaction with $CuCN / KCN$ gives 4- methyl benzonitrile, which on hydrolysis gives $p$-toluric acid.