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Q. Which of the following has non-zero dipole moment ?

Chemical Bonding and Molecular Structure

Solution:

This is an asymmetric structure.
Structure of (b) is symmetrical. Here the resultant dipole moments of bonds of 2 'Br' atoms with 'P' get cancelled with the dipole moment of another P - Br bond and the dipole moments of both P - Cl bonds also gets cancelled.

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