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Q. Which of the following group has maximum hyperconjugation effect but minimum inductive effect

Organic Chemistry – Some Basic Principles and Techniques

Solution:

$- CH _{3}$ show maximum hyperconjugation effect but minimum inductive inductive effect.
For Hyperconjugation :- $C-H$ bond energy should be low (more $\propto- H$ more hyper conjugation with less $C-H$ bond energy)
For Inductive Effect :- no. of carbon and branching increases inductive effect.