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Q. Which of the following does not give carbylamine test?

Rajasthan PMTRajasthan PMT 2004

Solution:

Dimethyl amine $\left( CH _{3}\right)_{2} NH$ does not give carbyl-amine reaction. Carbylamine reaction is the characteristic reaction of alephatic and aromatic primary amines. $R- NH _{2}+ CHCl _{3}+3 KOH \ce{->[{\Delta}]} \underset{\text { isocvanide}} {R- NC} 3KCl+3H_2O$