We know PV $= nRT$ or $\frac{1}{ T }=\frac{ nR }{ PV }$
Since, $P$ is constant, $P \Delta V = nR \Delta T$
(or) $\frac{\Delta V }{\Delta T }=\frac{ nR }{ P }$
Coefficient of volume expansion $\alpha_{v}=\frac{\Delta V}{V \Delta T}$
$\alpha_{v}=\frac{ nR }{ PV }=\frac{1}{ T }$