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Q. Which of the following correspond $(s)$ has '$Z$' configuration?Chemistry Question Image

BITSATBITSAT 2008

Solution:

When the groups with higher priority (ie, with high atomic number) are present on same side of double bond, then the configuration is $Z$ but when present on opposite side of double bond, the configuration is $E$. (Priority: $Br > CI$ and $CH _{3}> H$ ) Hence, compound (i) and (iii) have $(Z)$ configuration.

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