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  4. Which of the following compounds reacts with NaNO2 and HCl at 0 - 4°C to give alcohol/phenol?

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Q. Which of the following compounds reacts with $NaNO_2$ and $HCl$ at $0 - 4^°C$ to give alcohol/phenol?

Amines

Solution:

Aliphatic primary amines react with $NaNO_2$ and $HCl$ to yield alcohols.
$C_2H_5NH_2 + HNO_2(NaNO_2 + HCl) \rightarrow C_2H_5OH + N_2 +H_2O$