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Chemistry
Which of the following compounds are aromatic?
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Q. Which of the following compounds are aromatic?
KEAM
KEAM 2018
Hydrocarbons
A
A, B
48%
B
A, B, C
17%
C
B, C
15%
D
B, C, D
11%
E
A, B, D
11%
Solution:
Structure (a) has two $\pi$ -bonds and one lone pair of electrons over $N$ -atom and has planer structure.
Thus, is an aromatic compound.
(b) The structure (b) also contain two $\pi$ -bonds and one lone pair of electrons. Thus, follow Huckel' s rule. The structure is cyclic and planer.
$\therefore $ (b) is also an aromatic compound.
(c) The structure (c) has only $2 \pi$ -bonds and do not follow Huckel' s rule. So, it not an aromatic compound.
(d) Structure (d) also contain only two $\pi$ -bonds, thus do not follow Huckel' s rule and is not an aromatic compound.