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Q. Which of the following compounds are aromatic?Chemistry Question Image

KEAMKEAM 2018Hydrocarbons

Solution:

Structure (a) has two $\pi$ -bonds and one lone pair of electrons over $N$ -atom and has planer structure.

Thus, is an aromatic compound.

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(b) The structure (b) also contain two $\pi$ -bonds and one lone pair of electrons. Thus, follow Huckel' s rule. The structure is cyclic and planer.

$\therefore $ (b) is also an aromatic compound.

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(c) The structure (c) has only $2 \pi$ -bonds and do not follow Huckel' s rule. So, it not an aromatic compound.

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(d) Structure (d) also contain only two $\pi$ -bonds, thus do not follow Huckel' s rule and is not an aromatic compound.