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Q.
Which of the following cannot act as reducing agent?
AMUAMU 2003
Solution:
A reducing agent may be defined as a substance, the oxidation number of whose atom increases. Reduction is accompanied by an increase in oxidation number of the reducing agent. Carbon belongs to IV A group. So, its maximum oxidation number is $+4$. In $ CO_{2} $ the oxidation number of carbon is $+4$ which cannot be further, increased. Hence, $ CO_{2} $ cannot act as reducing agent. While the maximum oxidation number of nitrogen, sulphur and chlorine are $+5, + 6$ and $+ 7$ respectively. In $ NO_{2},CO_{2} $ and $ ClO_{2} $ the O.N. of nitrogen, sulphur and chlorine is $+4$. Which can be further, increased. So, they can act as a reducing agent.