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Chemistry
Which has the minimum freezing point ?
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Q. Which has the minimum freezing point ?
UPSEE
UPSEE 2005
A
One molal $ NaCl\, aq. $ solution
B
One molal $ CaCl_2\, aq. $ solution
C
One molal $ KCl \,aq. $ solution
D
One molal urea $ aq. $ solution
Solution:
Depression in freezing points is colligative property. The solute which produces highest number of ions will have minimum freezing point.
(a) One molal $NaCl$ aqueous solution
$\to \, Na ^{+}+ Cl ^{-}$
$\therefore $ 2 ions / molecule
(c) one molal KCl aqueous solution
$\to K ^{+}+ Cl ^{-}$
$\therefore $ 2 ions/ molecule
(d) One molal urea aqueous solution$\to$ no dissociation
(b) One molal $CaCl _{2}$ solution
$CaCl _{2} \to Ca ^{2+}+2 Cl ^{-}$
$\therefore \,3$ ions/molecule
$\because \, CaCl _{2}$ solution has highest number of ions
$\therefore $ it has lowest freezing point.