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Q. Which has highest pH:-

AIPMTAIPMT 2002Equilibrium

Solution:

Hint: From the composition of salt we can find out whether it is weak acid or base.
Explanation:
NH4Cl is acidic since it is salt of strong acid (HCl) and weak base (NH4OH).
pHNH4C1<7
NaNO3 is neutral since it salt of strong acid (HNO3) and strong base (NaOH).
pHNaNO3=7
CH3COOK is weakly basic since it the salt of a weak acid (CH3COOH) and strong base (KOH)
pHCH3COOK>7
Na2CO3 is the stronger base because it is the salt of weak acid H2CO3 and strong acid NaOH
pHNa2CO3>pHCH3COOK>7