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Q. Which combination of following terms is matched correctly?
(I) Intermolecular forces
(II) Latent heat of vaporization
(III) Vapour pressure
I II III
(a) High Weak Small
(b) High Strong Large
(c) Low Weak Large
(d) Low Strong Small

Solutions

Solution:

Liquid $\rightleftharpoons$ Vapour
(a) If vapour pressure is high, it means equilibrium is in forward side. This is attained when intermolecular forces holding the molecules are of weak nature. Low heat is required to convert liquid into vapour. Thus, (a) is correct
(b) Thus, incorrect
(c) When vapour pressure is low, it means intermolecular forces are strong hence (c) is incorrect
(d) When, vapour pressure is low, intermolecular forces are strong, hence large heat is required thus, (d) is incorrect