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Q.
Which amongst the following is the most stable carbocation?
AIPMTAIPMT 2005Organic Chemistry – Some Basic Principles and Techniques
Solution:
$CH _{3}- \overset{\underset{|}{C}H_3}{\underset{\overset{|}{C}H_3}{C^+}}$is the most stable carbocation. It is a tertiary carbocation.
The order of carbocation stability is tertiary $>$ secondary $>$ primary $>$ methyl.
Greater is the number of alkyl groups attached to $C$ atom bearing positive charge, greater is the carbocation stability.