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Q. Which among the following statements is incorrect for manganate and permanganate ions?

AP EAMCETAP EAMCET 2020

Solution:

image
$\Rightarrow $ Tetrahedral
$\Rightarrow d \pi(M n)-p \pi(O)$ is present.
$\Rightarrow $ Paramagnetic, due to presence of one unpaired $d$-electron of
$Mn ^{+6}\left(3 d'\right)$ of $MnO _{4}{ }^{2-}$
$\Rightarrow $ Oxidising agent.
image
$\Rightarrow $ Tetrahedral
$\Rightarrow d \pi(M n)-p \pi(O)$ is present.
$\Rightarrow $ Diamagnetic, due to the absence of unpaired $d$-electron in $Mn^{+7}\left(3 d^{0}\right)$
of $MnO_{4}^{-}$
$\Rightarrow $ Stronger oxidising agent.