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Chemistry
When K2Cr2O7 is converted into K2CrO4 , the change in oxidation number of chromium is :
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Q. When $ K_2Cr_2O_7 $ is converted into $ K_2CrO_4 $ , the change in oxidation number of chromium is :
UPSEE
UPSEE 2005
A
$ 0 $
B
$ 5 $
C
$ 7 $
D
$ 9 $
Solution:
The sum of oxidation state of all elements in a compound is always zero.
Let, oxidation state of $Cr$ in $K _{2} Cr _{2} O _{7}=x$
$(+1 \times 2)+2 x+(-2 \times 7)=0 $
or $+2+2 x-14=0$
$\therefore \, x=+6$
Let oxidation sate of $Cr$ in $K _{2} CrO _{4}=x$
$\therefore \,+1 \times 2+x+(-2 \times 4)=0$
$2+x-8=0 $
$\therefore \, x=6$
$\therefore $ Change in oxidation state of $Cr$ is zero when it changes from $K _{2} Cr _{2} O _{7}$ to $K _{2} CrO _{4}$