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Q. When chlorine reacts with dil. $NaOH$ under cold conditions, the oxidation state of chlorine changes from zero to

J & K CETJ & K CET 2008The p-Block Elements - Part2

Solution:

When chlorine reacts with dilute and cold $NaOH$, sodium chloride and sodium hypochloride are formed.
$2 NaOH$ (cold) $+ Cl _{2} \rightarrow NaCl + \underset{\text{soldium hypochloride}}{NaClO} + H _{2} O$
Let oxidation state of $Cl$ in $NaCl$ is $x$.
$NaCl +1 + x =0 x=-1$
Let oxidation state of $Cl$ in
$NaClO$ is $x . NaClO$
$ +1 + x -2 =0$
$x -1=0$
$x = + 1$
$\therefore $ Oxidation states of chlorine changes from
$0$ to $-1$ and $+1 .$