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Q. When aqueous NaOH is added to an aqueous solution of chromium (III) ions, a green blue precipitate is first formed which re-dissolves to give a green solution. The green colour is due to

NTA AbhyasNTA Abhyas 2020Coordination Compounds

Solution:

When aqueous solution of NaOH is added to aqueous solution of Cr (III) ion it produces image

Which further redissolves in aq. NaOH (in excess) to produce dark green solution due to formation of $\left(\left[\text{Cr} \left(\text{OH}\right)_{4}\right]\right)^{-}$

image