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Q. When $10\, m L$ of an aqueous solution of $F e^{2+}$ ions was titrated in the presence of dil $H _{2} SO _{4}$ using diphenylamine indicator, $15\, mL$ of $0.02\, M$ solution of $K _{2} Cr _{2} O _{7}$ was required to get the end point. The molarity of the solution containing $F e^{2+}$ ions is $x \times 10^{-2} M$. The value of $x$ is __________.(Nearest integer)

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Solution:

milli-equivalents of $F e^{2+}=$ milli-equivalents of $K _{2} Cr _{2} O _{7}$
$M \times 10 \times 1=0.02 \times 15 \times 6$
$M=0.18=18 \times 10^{-2} M$