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Q. When $1 \,kg$ of ice at $0^{\circ} C$ melts to water at $0^{\circ} C$, the resulting change in its entropy, taking latent heat of ice to be $80 \,cal /{ }^{\circ} C$, is

AIPMTAIPMT 2011Thermodynamics

Solution:

Here
$ L =80\, cal / k$
$ m =1 \, kg =1000 \, g $
$ T =273 \, K$
Heat absorbed in change of phase $Q=m L$
$\Delta Q =1000 \times 80=8 \times 10^{4} \, cal$
$S =\frac{\Delta Q}{T}$
$=\frac{8 \times 10^{4}}{273} $
$=293 \, cal / k$