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Chemistry
When 0.1 mole of a gas absorbs 41.75 J of heat, the rise in temperature occurs equal to 20°C. The gas must be
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Q. When 0.1 mole of a gas absorbs 41.75 J of heat, the rise in temperature occurs equal to $20^\circ$C. The gas must be
Thermodynamics
A
triatomic
7%
B
diatomic
63%
C
polyatomic
11%
D
monoatomic
19%
Solution:
Atomicity of gas is deiced by the ratio $C_{P} / C_{V}$. $q=n \dot{C}_{V} \Delta T$
Thus molar heat capacity at constant volume $C_{V}=\frac{q}{n \Delta T}$
$=\frac{41.75 J}{(0.1 mol )(20 K )}$
$20.88 JK ^{-1} mol ^{-1}$
For an ideal gas, $C_{P}-C_{V}=R$
or $C_{P}=R+C_{V}$
$=(8.314)+(20.88)$
$=29.19 J K^{-1} mol ^{-1}$
Finally, $\frac{C_{P}}{C_{V}}=\frac{29.19}{20.88}=1.40$
This implies than the gas is diatomic.