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Q. What is the product obtained when chlorine reacts with ethyl alcohol in the presence of $ NaOH$ ?

AIIMSAIIMS 2007

Solution:

When chlorine reacts with ethyl alcohol in the presence of $NaOH$, chloroform is obtained as a final product.
$CH _{3} CH _{2} OH + Cl _{2} \xrightarrow{\text { Oxidation }}\underset{\text{acetaldehyde}}{CH_3CHO +2HCl}$
$CH _{3} CHO +3 Cl _{2} \xrightarrow{\text { Chlorination }}\underset{\text{chloral}}{CCl_3CHO} +3HCl$
$CCl _{3} CHO + NaOH \xrightarrow{\text { Hydrolysis }}\underset{\text{chloroform}}{CHCl_3} +HCOONa$