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Q. What is the maximum concentration of equimolar solutions of $FeSO _{4}$ and $Na _{2} S$ so that when mixed in equal volumes, there is no precipitation of $FeS$ ? $\left( K _{ sp }\right.$ of $FeS$ $\left.=6.25 \times 10^{-18}\right)$

Equilibrium

Solution:

$s ^{2}=6.25 \times 10^{-18}$
$s =2.5 \times 10^{-9}$
$M =2 s=2 \times 2.5 \times 10^{-9}$
$=5.0 \times 10^{-9} M$